乌洛托品化学品安全技术说明书(MSDS)
化学品名称：
Chemical Product：
化学品中文名称：六亚甲基四胺
Chemical Chinese Name：六亚甲基四胺
化学品英文名称：hexamethylenetetramine
Chemical English Name：hexamethylenetetramine
分子式： C 6 H 12 N 4
Molecular Formula：C 6 H 12 N 4
分子量：140.18
Molecular Weight：140.18
成分/组成信息：
Composition，Information on Ingredients：
主要成分：纯品
Key Component： Technical-pure Grade
CAS No.： 100-97-0
危险性概述：
Hazards Identification：
健康危害：生产条件下，主要引起皮炎和湿疹。皮疹多为多形性，奇痒，初起局限于接触部位，以后可蔓延，甚至遍及全身。
Health Hazard: The main cause of dermatitis and eczema during production conditions. Skin rashes are polymorphic, extremely tickle. It starts with the contacting area then spread even throughout the whole body.
急救措施:
First Aid Measures:
皮肤接触：脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。
Skin: Remove contaminated clothing and wash the skin wi t h SOAP and water thoroughly.
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。就医。
Eyes: L ifting the eyelid, with flowing water or normal saline flush. Seek medical advice.
吸入：迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工呼吸。就医。
Inhalation: Rapidly run away from the site to the fresh air. Keep respiratory tract clear. Have oxygen therapy if breathing is difficult. Take artificial respiration immediately, if breathing stops. Seek medical advice.
食入：饮足量温水，催吐。就医。
Ingestion: Drink enough warm water and induce vomiting. Seek medical advice.
消防措施:
Fire Fighting Measures:
危险特性：遇明火有引起燃烧的危险。受热分解放出有毒的氧化氮烟气。与氧化剂混合能形成爆炸性混合物。具有腐蚀性。
Hazard characteristics: It will cause burning if meets with fire. Heat decomposition emi t s toxic nitrogen oxide gas. Mixed with the oxidizer can form explosive mixtures. Corrosive.
灭火方法：喷水冷却容器，可能的话将容器从火场移至空旷处。
Fire extinguishing methods: Spray water to cool the container. Move the container from the fire scene to the open air if possible.
灭火剂：泡沫、二氧化碳、雾状水、砂土。
Extinguishing media: foam, carbon dioxide, water fog, sand.
泄漏应急处理:
Accidental Release Measures:
应急处理：隔离泄漏污染区，限制出入。切断火源。建议应急处理人员戴防尘面具（全面罩），穿防毒服。不要直接接触泄漏物。
Emergency handling: Leakage of contaminated areas should be isolated, restricted access, and cut off the fire source. Emergency personnel should wear a dust mask (full cover), and put anti-virus service. Do not have direct contact wi t h leaks.
小量泄漏：用洁净的铲子收集于干燥、洁净、有盖的容器中。
A small leak: Collect in a dry, clean and lidded container with a clear shovel.
大量泄漏：用塑料布、帆布覆盖。使用无火花工具收集回收或运至废物处理场所处置。
A large number of leaks: Cover that by plastic tarps and canvas. Collect that by non-sparking tools or transport to disposal of waste disposal sites.
操作处置与储存:
Handling and Storage:
储存注意事项：储存于阴凉、通风的库房。远离火种、热源。包装密封。应与氧化剂、酸类分开存放，切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有合适的材料收容泄漏物。
Store Note: Store in a cool, well ventilated warehouse. Keep away from fire and heat. Sealed Package. Should be stored separately to oxidants, acid class and avoid mixing storage. Take Explosion-proof type lighting and ventilation. Prohibition of the use of mechanical equipment and tools which are easy to produce sparks. Storage areas should be provided with the appropriate material to deal with the leakage.
接触控制/个体防护:
Exposure Controls, Personal Protection:
工程控制：密闭操作，局部排风。
Engineering controls: Airtight operations, local exhaust ventilation.
呼吸系统防护：粉尘浓度较高的环境中，佩戴自吸过滤式防尘口罩。必要时，建议佩戴自给式呼吸器。
Respiratory protection: In environments with high dust concentration, wearing a self-priming filter type dust respirator. If necessary, recommends wearing self-contained breathing apparatus.
眼睛防护：戴化学安全防护眼镜。
Eye protection: wear chemical safety glasses.
身体防护：穿防毒物渗透工作服。
Body protection: Wear poison infiltration of overalls.
手防护：戴一般作业防护手套。
Hand protection: Wear operating protective gloves.
其他防护：工作现场禁止吸烟、进食和饮水。工作完毕，淋浴更衣。注意个人清洁卫生。
Other protection: No smoking, eating and drinking water. Take a shower and change clothes after finishing work. Pay attention to personal hygiene.
理化特性:
Physical and Chemical Properties:
外观与性状：白色细粒状结晶，味初甜后苦。
Appearance and Odor: Whi t e fine-granular Crystal, taste sweet early and bitter later.
熔点(℃)：263(升华)
Melting point (℃): 263( sublimation)
相对密度(水=1)： 1.27
Relative density ( Water =1) ：1.27
燃烧热(kJ/mol)：239.7
Heat of combustion (kJ/mol) ：239.7
溶解性：溶于水、乙醇、氯仿、四氯化碳，不溶于乙醚、石油醚、芳烃。
Solubility: soluble in water, ethanol, chloroform, carbon tetrachloride, not soluble in ether, petroleum ether, and aromatic hydrocarbons.
主要用途：用作纺织品的防缩整理剂、亚氯酸钠漂白活化剂、防水剂CR的缓冲剂等。
Main use: use as shrink-proof finishing of textiles, waterproofing agent, sodium chlorite bleaching Activator CR Buffering etc.
稳定性和反应活性：
Stability and Reactivity：
禁配物：强氧化剂、强酸。
Ban of distribution: strong oxidizing agents, strong acids.
毒理学资料：
Toxicological Information：
急性毒性：LD50：9200 mg/kg(大鼠静脉)LC50：无资料
生态学资料：
Ecological Information：
废弃物性质：
Disposal Considerations:
废弃处置方法：处置前应参阅国家和地方有关法规。建议用焚烧法处置。焚烧炉排出的氮氧化物通过洗涤
器除去。
Disposal Method: Refer to the relevant national and local regulations before disposal. Incineration method recommended. Dispose the nitrogen oxide from incinerator emissions by scrubbers.
运输信息:
Transportation Information:
危险货物编号：41528
Hazardous goods #: 41528
UN编号：1328
UN #: 1328
包装类别：O53
Package Type: O53
包装方法：螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶（罐）外普通木箱；螺纹口玻璃瓶、塑料瓶或镀锡薄钢板桶（罐）外满底板花格箱、纤维板箱或胶合板箱。
Packing Method: Thread-covered glass bottles, iron-covered glass bottles, plastic bottles or metal barrel (tank), Wooden boxes; threaded glass bottle, plastic bottle or tin plated steel barrel (tank), full floor take a plywood box, fiberboard box or boxes.
法规信息：
Laws and Regulations：
国内化学品安全管理法规：化学危险物品安全管理条例(1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则(化劳发[1992] 677号)，工作场所安全使用化学品规定([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定；常用危险化学品的分类及标志(GB 13690-92)将该物质划为第4.1类易燃固体。
Domestic regulations on chemical safety: Safety management of chemical dangerous goods Ordinance (1987 years 2 months 17 days of State publishing ) Chemical security rules for the implementation of regulations on the management of dangerous goods ( Dr [1992] 677 ) And safe use of chemicals in the workplace regulations ([1996] Ministry of Labor issued 423 ) Regulations for the safe use of hazardous chemicals, production, storage, transportation, handling, and so on are made corresponding provisions; commonly used classif ication and labels of dangerous chemicals (GB 13690-92) The substance is classified as 4.1 Flammable solids.