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CH4 emission and conversion from A2O and SBR processes in full-scale wastewater treatment plants

CH4 emission and conversion from A2O and SBR processes in full-scale wastewater treatment plants
CH4 emission and conversion from A2O and SBR processes in full-scale wastewater treatment plants

Journal of Environmental Sciences 26(2014)

224–230

https://www.doczj.com/doc/cd5808958.html,

Journal of Environmental Sciences

Available online at https://www.doczj.com/doc/cd5808958.html,

CH 4emission and conversion from A 2O and SBR processes in full-scale wastewater treatment plants

Yan Liu,Xiang Cheng,Xiaoxiu Lun ?,Dezhi Sun

College of Environmental Science and Engineering,Beijing Forestry University,Beijing 100083,China

a r t i c l e i n f o

Article history:

Special issue:Progress and prospects of atmospheric environmental science in China

Keywords:CH 4emission

production and consumption wastewater treatment plant A 2O SBR

DOI :10.1016/S1001-0742(13)60401-5

a b s t r a c t

Wastewater treatment systems are important anthropogenic sources of CH 4emission.A full-scale experiment was carried out to monitor the CH 4emission from anoxic /anaerobic /oxic process (A 2O)and sequencing batch reactor (SBR)wastewater treatment plants (WWTPs)for one year from May 2011to April 2012.The main emission unit of the A 2O process was an oxic tank,accounting for 76.2%of CH 4emissions;the main emission unit of the SBR process was the feeding and aeration phase,accounting for 99.5%of CH 4emissions.CH 4can be produced in the anaerobic condition,such as in the primary settling tank and anaerobic tank of the A 2O process.While CH 4can be consumed in anoxic denitri?cation or the aeration condition,such as in the anoxic tank and oxic tank of the A 2O process and the feeding and aeration phase of the SBR process.The CH 4emission ?ux and the dissolved CH 4concentration rapidly decreased in the oxic tank of the A 2O process.These metrics increased during the ?rst half of the phase and then decreased during the latter half of the phase in the feeding and aeration phase of the SBR process.The CH 4oxidation rate ranged from 32.47%to 89.52%(mean:67.96%)in the A 2O process and from 12.65%to 88.31%(mean:47.62%)in the SBR process.The mean CH 4emission factors were 0.182g /ton of wastewater and 24.75g CH 4/(person ·year)for the A 2O process,and 0.457g /ton of wastewater and 36.55g CH 4/(person ·year)for the SBR process.

Introduction

Methane (CH 4),which is a major greenhouse gas,plays an important role in global warming.CH 4is the second most important greenhouse gas following carbon dioxide because its radiative forcing among all of the long-lived greenhouse gases accounts for approximately 20%of the total radiative forcing.Moreover,the global warming potential of CH 4is 25times that of CO 2over 100years (IPCC,2007;Shindell et al.,2009).From pre-industrial times to the early 1990s,the CH 4concentration more than doubled from 0.7to 1.7ppmV (Popatti et al.,1996;Etheridge et al.,1998).Although it decreased transitorily from 2000to 2006(Bousquet et al.,2006),the CH 4concentration has been increasing by approximately 7

?Corresponding

author.E-mail:lunxiaoxiu@https://www.doczj.com/doc/cd5808958.html,

ppb /year since 2007(Rigby et al.,2008).

CH 4is released into the atmosphere by a wide variety of sources,both natural and anthropogenic.According to the data of the total greenhouse gas emission,about 48%of CH 4emission is caused by anthropogenic sources (IPCC,2007).Anthropogenic sources of CH 4emission include fossil fuels,domestic ruminants,waste decomposition,rice cultivation,biomass burning,etc.(Khalil,2000).Data from the IPCC (2007)estimate that approximately 4%of the total anthropogenic CH 4emission comes from wastew-ater treatment.Given the increasing rate of wastewater treatment,the volume of wastewater treated is increasing in China.The anoxic /anaerobic /oxic process (A 2O)and the sequencing batch reactor activated sludge process (SBR)are both popular wastewater treatment techniques.The two processes are employed on a large scale in China and account for 24%and 12%of all kinds of wastewater treatment plants (WWTPs),respectively (Xie and Wang,

Journal of Environmental Sciences2014,26(1)224–230225

2011).

A large amount of CH4can be produced in sewer

systems(Guisasola et al.,2008),and a part of this CH4

can be oxidized in an activated sludge biological treatment

process.Czepiel et al.(1993)?rst studied the CH4emis-

sions from a simple WWTP in the USA and estimated the

emission factors.Wang et al.(2011)measured the CH4

emissions from a typical full-scale A2O process municipal

WWTP in China and identi?ed the major emission sources.

However,until now,there has been no literature that has

reported the CH4conversion and the actual value in the

A2O and SBR processes.

In this study,a full-scale experiment was carried out

to monitor CH4emission from A2O and SBR WWTPs

to determine the CH4emission strength of each unit and

the emission characteristic of the main emission units.In

addition,the CH4production and consumption of each

unit were analyzed.The CH4oxidation rate and emission

factors from the two processes were determined.

1Methods

1.1Full-scale plants

This experiment was conducted from May2011to April

2012at two full-scale municipal WWTPs in the eastern

(GBD WWTP)and southwestern(WJC WWTP)parts

of Beijing,China.The GBD WWTP has a treatment

capacity of5×105m3/day and serves a population of approximately1,200,000.The in?uent is primarily domes-

tic wastewater with an average COD concentration of400

mg/L and an average suspended solids(SS)concentration

of250mg/L.The e?uent COD and SS concentration are

less than50mg/L and30mg/L,respectively.The WJC

WWTP has a treatment capacity of8×104m3/day and serves a population of approximately231,000.The in?uent is primarily domestic wastewater with an average COD concentration of500mg/L and an average SS concentra-tion of250mg/L.The e?uent COD and SS concentration are less than35mg/L and15mg/L respectively.

The GBD WWTP adopts the A2O process consisting of the anoxic step,the anaerobic step and the oxic step. The wastewater that passes through the aerated grid tanks and primary settling tanks?ows into the A2O plug?ow reactor.In the A2O process,the wastewater?rst?ows into the anoxic tank and then?ows into the anaerobic tank and the oxic tank.The e?uent of the oxic tank, which contains plenty of activated sludge,passes into the secondary settling tank to separate the activated sludge from the treated wastewater.Some of the settled sludge is recycled back to the beginning of the A2O process(anoxic tank)to maintain the sludge concentration of the A2O process.The WJC WWTP adopts the SBR process.The in?uent that?ows into the swirl girt tank to removal solids is distributed to the SBR biological treatment tanks by the sewage distribution tank.The biological treatment process includes six cycles per day,and each cycle is divided into three phases,which are the feeding and aeration phase,the settling phase,and the decanting phase.The duration of each phase is2,1,and1hr,respectively,and the cycle time is4hr.

1.2Samplings from full-scale plants and the CH4?ux

calculation

The main wastewater treatment processing units of the GBD and WJC WWTPs are all open to the atmosphere. The CH4?uxes were measured from each frame unit of the two WWTPs.Sampling was carried out once per month from May2011to April2012.The sampling point positions and the number of sampling points or sampling frequency are shown in Table1.The water surfaces of the sampling positions are divided into two categories,aerated and nonaerated surfaces.The number of sampling points of A2O was determined by the water surface area and the dissolved oxygen variaton of each sampled unit,and

Process style units Processing Water surface Water Number of sampling

areas(m2)surfaces type points or sampling frequency

A2O Aerated grit tanks504Aerated2

Primary settling tanks25200Nonaerated2

Anoxic tanks3564Nonaerated2

Anaerobic tanks3564Nonaerated2

Oxic tanks24945Aerated6

Final clari?er tanks23562Nonaerated2

SBR Swirl grit tanks28Nonaerated2

Sewage distribution tanks32Nonaerated2

Feeding and aeration phase11872Aerated4(once half an hour)

Settling period11872Nonaerated2

Decanting period11872Nonaerated2

226Journal of Environmental Sciences2014,26(1)224–230

the sampling frequency was determined by the duration of each phase in the SBR process.The sampling methods were described by Czepiel et al.(1993)and Wang et al. (2011).

1.2.1Methods to measure the CH4?ux from aerated

units

A bag technique was used to measure the CH4?uxes from the aerated liquid surfaces.A90L cubic polyethylene sample bag,fastened to the inside of a plastic support frame,was used to collect gas samples from the agitated surface of each aerated unit.To collect samples,the bag was?rst collapsed and emptied of ambient air,and the plastic support frame was then immersed several inches in the water.The dissolved methane within the wastewater was transferred to the mechanically distributed air by dif-fusion and then?lled the collection bag.Gas samples were then withdrawn from the bag into200-mL aluminum foil plastic bags.The gas exchange?ux,E(mass/(area·time)), was calculated by Eq.(1).

E=ρ×c×Q/A(1) where,ρ(g/m3)is the density of the CH4at the temperature recorded in the sample bag,c(m3/m3)is the sample gas

concentration,Q(m3/day)is the di?used air?ow of the sampling surface area,and A(m2)is the sampling surface area.

1.2.2Methods to measure the CH4?ux from non-

aerated units

An emission isolation?ux chamber was used to measure the?uxes from nonaerated wastewater surfaces.The di-ameter and volume of the cylindrical stainless steel?ux chamber were0.6m and37.7L,respectively,with a sampling area of0.126m2.The?ux chamber was?oated on the liquid surface with a thermocouple probe mounted inside to measure the enclosed air temperature.Floats made from tires were fastened to the?ux hood’s sides,and the?ux hood was manually held in place during sampling to minimize chamber movement due to surface turbulence. The speci?c sampling site was1m from the bank of each processing unit or was set under the center of the raised walkway across the unit tank if available.A battery-operated blower circulated the air within the chamber and through a closed loop of the tube from which the headspace air samples were withdrawn.Samples were collected in 200-mL aluminum foil plastic bags at10-min intervals for 40min.The CH4exchange?ux,E,from the liquid surface in the static?ux hood was calculated using Eq.(2).

E=V/A×ρ×(d c/d t)(2) where,V(m3)is the volume of the?ux hood,A(m2) is the enclosed surface area,ρ(g/m3)is the density of the CH4gas at the temperature recorded in the hood, and d c(m3/m3)/d t(day)is the linear increase in the CH4 concentration in the hood during the sampling period.

1.2.3Dissolved CH4gas samplings and calculations of

the wastewater

To collect samples of the gas dissolved in wastewater,the headspace gas method was used as described by Kimochi et al.(1998).A2.5-L water collection device was used to collect the wastewater in each tank.Three hundred milliliters of water was sealed into a300-mL glass bottle, and1mL of20mmol/L mercury(II)chloride was added to prevent biological CH4oxidation.One hundred milliliters of N2was continuously injected into the bottle to replace the water inside the bottle.After vigorous shaking,the bottle was left at room temperature for1hr without moving it.The resulting gas phase in the bottle was collected as a gas sample.The dissolved CH4concentration was then calculated based on Henry’s Law using the equilibrated headspace CH4concentration.

1.3Analytical methods of CH4concentration in the gas

samples

All of the gas samples were analyzed within12hr using an Agilent7890A gas chromatograph equipped with a ?ame ionization detector(GC-FID).The airtightness of the aluminum foil plastic bags was examined.In the12 hr intervals,the change in the CH4concentration in the aluminum foil plastic bags was less than1%.

2Results and discussion

2.1Flow-normalized CH4emission

CH4is generated in wastewater treatment systems in areas of a high biological oxygen demand and a low oxygen concentration,such as the sewer network,primary settling tanks,and sludge transfer lines,and can be emitted in the following units(Czepiel et al.,1993).Field measurements found that CH4emission occurred in every atmosphere-open wastewater treatment units,which were all measured. The?ow-normalized CH4emission from each unit was determined to?nd the key CH4emission unit and the emission order of each unit(Table2).

A wide range of CH4emissions was measured in every processing unit,which was the same as in previous reports (Czepiel et al.,1993;Wang et al.,2011).The CH4emission in aerated zones was higher than that in non-aerated zones. In the A2O process,the maximum CH4daily emission was calculated at the oxic tank.The CH4emission from the oxic tank accounted for76.2%of all processing units’emission.This proportion was di?erent from previous reports.The proportion reported by Wang et al.(2011)

Journal of Environmental Sciences 2014,26(1)224–230

227

Processes

Processing Flow-normalized unit

CH 4emission

(g /ton of wastewater)A 2O

Aerated grid tank 1.45×10?3–2.64×10?2Primary settling tank 6.20×10?3–1.28×10?1Anoxic tank 1.00×10?3–6.94×10?3Anaerobic tank 1.31×10?3–1.91×10?2Oxic tank

3.21×10?2–3.72×10?1Secondary settling tank 1.81×10?5–2.13×10?3SBR

Swirl grit tank

6.19×10?5–1.33×10?3Sewage distribution tank 3.38×10?5–1.27×10?3Feeding and aeration phase 8.70×10?2–1.59

Settling phase 1.01×10?5–5.54×10?4Decanting

1.06×10?5–9.12×10?4

was only from 27.3%to 42.5%,and there was no detailed description about the CH 4emission characteristic of the oxic tank.The diversity of the data might be attributed to the di ?erent sampling points and di ?erent area of the oxic tank.In the SBR process,the feeding and aeration phase had the maximum ?ow-normalized CH 4emission.The CH 4emission from the feeding and aeration phase accounted for 99.5%of all processing units’emission.There is no report about the CH 4emission in a full-scale SBR process.

2.2CH 4emission and conversion in the A 2O process 2.2.1Overall analysis

The average CH 4?ux from each unit and the correspond-ing dissolved CH 4concentration in the A 2O process are shown in Fig.1.The CH 4emission ?uxes re?ect the CH 4emission strength of the processing units.It has been reported that a signi?cant amount of CH 4could be produced because of the dissolved COD decomposition under an anaerobic condition in sewer systems (Guisasola et al.,2008).This led to a high dissolved CH 4concentra-

C H 4 f l u x (g /(m 2.d a y ))

D i s s o l v e d C H 4 (m g /L )

grid tank settling tank

tank tank tank

settling tank

Fig.1CH 4?ux and dissolved CH 4concentrations from the A 2O processes.

tion in the in?uent and the primary wastewater treatment processing units,including the aerated grid tank and the primary settling tank.The dissolved CH 4in the aerated grid tank was partly released into atmosphere rapidly by intensive mechanical aeration,causing a high CH 4emission ?ux.The CH 4emission ?ux,which was mainly determined by the undisturbed water surface rather than the intensive aeration,from the primary settling tank was not as high as the aerated grid tank.Because of slow water ?ow and no water turbulence for settling,anaerobic conditions might exist in the primary settling tank,and CH 4could be produced in this place.Therefore,the dissolved CH 4concentration in the primary settling tank was a little higher than that in the aerated grid tank,despite a great deal of CH 4being emitted in the primary settling tank.In the anoxic tank,there were three reasons for the rapid decrease in the dissolved CH 4concentration.Firstly,the return sludge ?owed into the beginning of the anoxic tank and diluted the dissolved CH 4of the wastewater from the primary settling tank;secondly,the CH 4could be used as an electron donor during the denitri?cation process (Ettwig et al.,2010;Raghoebarsing et al.,2006);thirdly,some of the dissolved CH 4in the anoxic tank could be emitted to the atmosphere.In the anaerobic tank,the dissolved CH 4concentration had a small increase,which proved the apparent CH 4production in this unit (Toyoda et al.,2011).Given the same strength of water stirring,the CH 4?ux from the anaerobic tank was a little higher than that from the anoxic tank because of the higher dissolved CH 4concentration in the anaerobic tank.The high CH 4?ux and low dissolved CH 4concentration in the oxic tanks were attributed to the following three phenomena:Firstly,the high su ?cient aeration stripped most of the CH 4dissolved in the wastewater into the atmosphere (Wang et al.,2011);Secondly,much of the dissolved CH 4in the oxic tank was oxidized (Daelman et al.,2012);And thirdly,no CH 4was produced in the oxic condition.Since there was nearly no CH 4after adequate mechanical aeration in the oxic tank,the CH 4?ux and dissolved CH 4concentration in the secondary settling tank were both at their lowest level.2.2.2Main unit:oxic tanks

The oxic tank had the highest CH 4emission and the largest area,so the CH 4emission from a di ?erent site of the oxic tank was not the same.There is no report about the CH 4emission characteristic of an oxic tank.Figure 2shows the variation of CH 4?uxes,dissolved CH 4concentrations and dissolved oxygen concentrations at six points of the oxic tank along the plug ?ow.The CH 4dissolved in wastewater was rapidly emitted,especially in front of the tank.The CH 4?ux decreased rapidly from 11.24g /(m 2·day)at the beginning to 0.06g /(m 2·day)at the end of the oxic tank.The dissolved CH 4concentration also decreased rapidly from 2.52×10?2to 5.83×10?4mg /L.The CH 4?ux and dissolved CH 4concentration remained stable near 80m,

228

Journal of Environmental Sciences 2014,26(1)224–230

01632

80

128

224

5

0.000.010.020.03C H 4 f l u x (g /(m 2.d a y ))

Aerobic distance in oxic tank (m)

D i s s o l v e d C H 4 (m g /L )

D O (m g /L )

Fig.2Dissolved oxygen concentrations,dissolved CH 4concentrations,and CH 4?uxes from six points of the oxic tank.

therefore the front part of the tank was the main source of CH 4emission.The DO concentration varied little from 0.69to 0.79mg /L during the ?rst 32m and gradually increased to 7.18mg /L at 80m.The variation of the DO concentration indicated that the removal of COD and the oxidation of CH 4caused a large DO consumption in the front of the oxic tank.A high DO concentration should be bene?cial to CH 4oxidation.The high DO concentration was achieved by su ?cient aeration.Although the CH 4may be easily oxidized in a high DO concentration,the high aeration also stripped the dissolved CH 4quickly.Further research should be carried out to ?nd the optimal aeration.2.3CH 4emission and conversion in the SBR process 2.3.1Overall analysis

The average of the CH 4?ux from each unit and the corresponding dissolved CH 4concentration in the SBR process are shown in Fig.3.In the primary treatment units,the swirl grit tank and the sewage distribution tank,the dis-solved CH 4concentrations were higher than those in other units in the A 2O process.Although the dissolved CH 4concentration did not di ?er much in the swirl grit tank and the sewage distribution tank,the CH 4?uxes of the former were much higher than that of the latter.The wastewater in the swirl girt tank was stirred intensively,and much of the dissolved CH 4was emitted,causing a high CH 4

?ux.

C H 4 f l u x (g /(m 2.d a y ))

D i s s o l v e d C H 4 (m g /L )

tank

distribution tank aeration

phase

phase Fig.3CH 4?ux and dissolved CH 4concentrations from the SBR

processes.

There was a relatively stilly water surface in the sewage distribution tank,so the dissolved CH 4was not di ?used easily.The CH 4?ux from the feeding and aeration phase was the highest in the whole SBR process because the dissolved CH 4was rapidly stripped out by the strength of the mechanical aeration.The dissolved CH 4concentration in the feeding and aeration phase was lower than that in the sewage distribution tank because of the high emission and oxidation.This result was like the variation in the oxic tank of the A 2O process.After the amount of CH 4decreased,the dissolved CH 4concentrations in the settling phase and decanting phase were ignored,and the CH 4?uxes were also at their lowest level.

2.3.2Main phase or unit:the feeding and aeration

phase The CH 4emission from the feeding and aeration phase of the biological treatment tank was the highest.Figure 4shows the CH 4?uxes,dissolved CH 4concentrations and dissolved oxygen concentrations at four time points of the feeding and aeration phase.The ?rst 60min period was feeding and aeration simultaneously,and the ?nal 60min period was only aeration.

The DO concentration in the whole feeding and aeration phase showed an up-down-up trend.At the beginning of the phase,the DO concentration increased because the rapid aeration and gradual feeding used up less DO.The DO concentration decreased when more and more wastew-ater was distributed into the biological tank.After the end of feeding at the 60min point,the DO concentration in-creased gradually until the end of this phase.The dissolved CH 4concentration increased during the ?rst half of the phase and decreased during the latter half of the phase.During the ?rst 30min period,the dissolved CH 4con-centration might increase in the wastewater distribution,and the average of the dissolved CH 4concentrations was 8.77×10?3mg /L.During the second 30min period,the dissolved CH 4concentration continued to increase because of continuous feeding,and the average of the dissolved

Journal of Environmental Sciences 2014,26(1)224–230

229

0-3030-6060-9090-1200

510152025

CH 4 flux

0.0060.008

0.010

Dissolved CH 4

Aerobic time in feeding and aeration phase (min)

C H 4 f l u x (g /(m 2

.d a y ))

D i s s o l v e d C H 4 (m g /L )

D O (m g /L )

Fig.4Dissolved oxygen concentrations,dissolved CH 4concentrations,and CH 4?uxes at four time points of the feeding and aeration phase in Feb 2012.

CH 4concentrations was 1.06×10?2mg /L.Much of the CH 4was oxidized and emitted during the feeding.There was no evidence proving the CH 4production during the intensive mechanical aeration,although it was reported that the anaerobic condition existed in the interior of the active aerobic granules (Chiu et al.,2007a,2007b).The dissolved CH 4concentration decreased gradually because of emission and oxidation after the feeding was stopped,and the average values were 6.17×10?3and 5.46×10?3mg /L,respectively,during the third and fourth 30min periods.The CH 4?uxes in Feb 2012(Fig.4)are 12.96,23.07,5.27,and 3.59g /(m 2·day)for the four time periods respectively,showing the similar variation trend to the dissolve CH 4.The annual average values of the CH 4?uxes were 5.82,9.66,8.38,and 6.58g /(m 2·day),respectively,during the ?rst,second,third,and fourth 30min periods.

2.4Comparison of the CH 4emission from the A 2O and

SBR processes The main source of the CH 4emitted in the A 2O and SBR processes is the dissolved CH 4in the in?uent,although a little CH 4can be produced in the anaerobic tank of the A 2O process.The sizes of the CH 4emission factors mainly depend on the CH 4oxidation rate (oxidized CH 4quality /in?uent dissolved CH 4quality)and the in?uent dissolved CH 4concentration of the two processes.Since there is a variation of the operation modes in the A 2O and SBR processes,the CH 4oxidation rates are also di ?erent.The range of oxidation rates and emission factors of the A 2O and SBR processes were calculated (Table 3).

In the A 2O process,the mean dissolved CH 4concentra-tion in the in?uent was 0.592mg /L,and the mean CH 4oxidation rate was 67.96%.The CH 4oxidation mainly happened in the anoxic tank and the oxic tank,causing a high CH 4oxidation rate.The mean CH 4emission factors were 0.182g CH 4/ton of wastewater based on the ?ow and 24.75g CH 4/(person ·year)based on the capita.The ?ow-based emissions from the study of Wang et al.(2011)and Czepiel et al.(C1993)were 0.155and 0.14g CH 4/ton of wastewater;the per capita emissions were 11.3and 39g CH 4/(person ·year),respectively.The big di ?erence in the per capita emission factors was caused by the per capita water consumption and the dissolved CH 4concentration of the in?uent.In the SBR process,the mean dissolved CH 4concentration in the in?uent was 0.848mg /L,and the mean CH 4oxidation rate was 47.62%.The CH 4oxidation mainly happened in the feeding and aeration phase.Since there was only one phase for oxidation and a great deal of CH 4could be stripped out under the intensive mechanical aeration,the mean CH 4oxidation rate was relatively low.The mean CH 4emission factors were 0.457g CH 4/ton of wastewater based on the ?ow and 36.55g CH 4/(person ·year)based on the capita.

Since the sewage systems of these two plants were di ?erent,the dissolved CH 4concentrations in the in?uent were also di ?erent between the A 2O (mean 0.592mg /L)and SBR (mean 0.848mg /L)processes.In the A 2O pro-cess,the dissolved

CH 4concentration could decrease and partly be consumed at the anoxic tank because of use of denitri?cation.The oxic tank also consumed a great deal of CH 4because of aeration.The hydraulic retention time of the oxic tank in the A 2O process was approximately 10hr,and the wastewater would remain for 3.5hr until the CH 4

Dissolved CH 4Oxidation CH 4emission CH 4emission in in?uent rate (%)

per unit in?uent

per capita

(mg /L)

(g CH 4/ton of wastewater)(g /(person ·year)A 2O 0.327–0.88232.47–89.520.066–0.4258.95–63.00SBR

0.642–1.02212.65–88.31

0.088–0.815

8.33–66.07

230Journal of Environmental Sciences2014,26(1)224–230

was emitted or oxidized.In the SBR process,oxidation could only occur in the feeding and aeration phase,and the duration of the feeding and aeration phase was2hr. Compared with the SBR process,the CH4oxidation rate of the A2O process was high not only because of existence of the anoxic unit but also because of the long oxidation time. The di?erence of the CH4production and consumption caused the discrepancy of the emission factors between the A2O and SBR processes.

3Conclusions

In the A2O process,the maximum CH4daily emission was calculated at the oxic tank,and the CH4daily emission from the oxic tank accounted for76.2%of all processing units’emission.In the SBR process,the feeding and aeration phase had the maximum CH4?ux,and the daily emission from the feeding and aeration phase accounted for99.5%of all processing units’emission.

In the A2O process,a small amount of CH4could be produced in the primary settling tank and the anaerobic tank and consumed in the anoxic tank and the oxic tank. The CH4emission?ux and the dissolved CH4concentra-tion rapidly decreased along the plug?ow in the oxic tank because of the sudden aeration and DO increase,and they were stable near80m.

In the SBR process,CH4could be consumed in the feeding and aeration phase.The CH4emission?ux and dissolved CH4concentration were increased during the ?rst half of the phase(feeding and aeration)and decreased during the latter half of the phase(only aeration).

The CH4oxidation rate ranged from32.47%to89.52% with a mean value of67.96%in the A2O process and from12.65%to88.31%with a mean value of47.62%in the SBR process.The mean CH4emission factors were 0.182g CH4/ton of wastewater based on the?ow and 24.75g CH4/(person·year)based on the capita in the A2O

process.The mean CH4emission factors were0.457g CH4/ton of wastewater based on the?ow and36.55g CH4/(person·year)based on the capita in the SBR process.

Acknowledgments

This work was supported by the Fundamental Research Funds for the Central Universities,China(No.TD2011-22),the China Welfare Funds for Environmental Protection (No.201009053),the Beijing Municipal Science and Technology Commission(No.Z111100058911003)and the National Natural Science Fundation of China(No. 51008023,51078034,51278051).r e f e r e n c e s

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点击登陆,进入软件,

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用友T软件系统操作手 册 Pleasure Group Office【T985AB-B866SYT-B182C-BS682T-STT18】

用 友 T+ 软 件 系 统 操 作 手 册 版本号:目录

一、系统登录 、下载T+浏览器 首次登陆需要用浏览器打开软件地址,即:(一般服务器默认设置,具体登陆地址请参考实际配置),第一次登陆会提示下载T+浏览器,按照提示下载安装T+浏览器,然后打开T+浏览器,输入软件登陆地址。 ,T+浏览器, 、软件登陆 按键盘上的“回车键(enter)”打开软件登陆页面,如下: 选择选择“普通用户”,输入软件工程师分配的用户名和密码,选择对应的账套,以下以demo为例,如下图: 点击登陆,进入软件, 二、基础档案设置 、部门、人员档案设置 新增的部门或者人员在系统中可按照如下方法进行维护, 、往来单位设置 供应商客户档案的添加方法如下: 添加往来单位分类: 、会计科目及结算方式设置 会计科目: 系统预置170个《2013小企业会计准则》科目,如下:

结算方式,如下: 三、软件操作 、凭证处理 填制 进入总账填制凭证菜单,增加凭证,填制摘要和科目,注意有辅助核算的会计科目, 以下为点开总账的处理流程图: 如若现金流量系统指定错误,可按照以下步骤修改: 凭证在没有审核时,可以直接在当前凭证上修改,然后点击“保存”完成修改; 凭证审核 进入总审核凭证菜单下,如下图: 选择审核凭证的会计期间: 、凭证记账 进入凭证菜单下的记账菜单, 、月末结转 期间损益结转 四、日常帐表查询与统计 、余额表 用于查询统计各级科目的本期发生额、累计发生额和余额等。传统的总账,是以总账科目分页设账,而余额表则可输出某月或某几个月的所有总账科目或明细科目的期初余额、本期发生额、累计发生额、期末余额,在实行计算机记账后,我们建议用户用余额表代替总账。

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