第４０卷第６期２０１７年１２月
火炸药学报
ＣｈｉｎｅｓｅＪｏｕｒｎａｌｏｆＥｘｐｌｏｓｉｖｅｓ＆Ｐｒｏｐｅｌｌａｎｔｓ
DOI：１０．１４０７７／j．issn．１００７-７８１２．２０１７．０６．０１０
用弹簧探针法测试含硼铝炸药的爆轰性能
李兴隆１，２，刘清杰１，２，宋清官１，２，高大元１，２，郑保辉１，曹威１，２，肖春１，谭凯元１，２
（１．中国工程物理研究院化工材料研究所，四川绵阳６２１９００；２．中国工程物理研究院安全弹药研发中心，
四川绵阳６２１９００）
摘要：为探索硼铝复合粉在热固PBX中的应用，以HMX为基，加入氧化剂高氯酸铵（AP）、硼铝复合粉和聚氨酯黏结剂，设计和制备了６种配方的含硼铝炸药；分别制备３种带壳体及３种不带壳体的Φ５０mm含硼铝炸药柱；用弹簧探针法测试了无壳体药柱和带壳体药柱的爆速，分别用经验公式和相对凹坑深度法计算了爆压，讨论了硼铝复合粉含量对其爆轰性能的影响。结果表明，炸药GH-４、GH-５和GH-６用手工浇注成型，Φ５０mm×１５０mm炸药柱密度在１．５３０～１．５７０g／cm３之间，爆速在６．９００～７．４００mm／μs之间，爆压约１９GPa，适用于含硼铝炸药配方筛选；炸药PF-１、PF-２和PF-３用真空振动浇注成型，Φ５０mm×１１０mm炸药柱密度约１．６９３g／cm３，爆速在７．８００～８．０００mm／μs之间，爆压约２４GPa。炸药PF-３中含质量分数２０％、硼铝质量比１∶１的复合粉，含金属炸药的组合效应使少量硼铝复合粉在反应区参加反应，其爆速和爆压值较其他配方高，表明弹簧探针法可作为炸药爆速测试的一种补充电测法，在无法实施铜箔探针法的情况下，可以考虑用弹簧探针法。
关键词：含硼铝炸药；弹簧探针法；爆速；爆压
中图分类号：TJ５５；T Q５６文献标志码：A文章编号：１００７-７８１２（２０１７）０６-００５９-０７ＤｅｔｏｎａｔｉｏｎＰｒｏｐｅｒｔｙＭｅａｓｕｒｅｍｅｎｔｏｆＥｘｐｌｏｓｉｖｅＣｏｎｔａｉｎｉｎｇＢ／ＡｌｂｙＳｐｒｉｎｇ
ＥｌｅｃｔｒｉｃＰｉｎＭｅｔｈｏｄ
LI Xing-long１，２，LIU Qing-j ie１，２，SONG Qing-g uan１，２，GAO Da-y uan１，２，ZHENG Bao-hui１，CAO Wei１，２，
XIAO Chun１，TAN Kai-y uan１，２
（１．Institute of Chemical Materials，CAEP，Mianyang Sichuan６２１９００，China；２．Robust M unitions Center，CAEP，
Mianyang Sichuan６２１９００，China）
Ａｂｓｔｒａｃｔ：To explore the application of B／Al compound powder in thermosetting plastic bonded explosive，six kinds of HMX based explosives containing boron（B）and aluminum（Al）were designed and prepared by adding oxidizer ammonium
p erchlorate（AP），B／Al compound powder and binder hydroxyl-terminated polybutadiene（HTPB）．Three kinds ofΦ５０mm explosive cylinders containing B／Al with shell and without shell were prepared respectively．The spring electric pin method was applied to measure detonation velocities of explosive cylinders with shell and without shell respectively．The detonation p ressures were calculated by the experienced formula and relative dent depth method respectively，the influence of B／Al compound powder content on detonation property was discussed．The results show that the explosives GH-４，GH-５，GH-６are solidified by manual casting，the densities ofΦ５０mm explosive cylinders are between１．５３０－１．５７０g／cm３，the deto-nation velocities are between６．９００－７．４００mm／μs，and the detonation pressures are about１９GPa，the manual casting is suitable for screening of explosive formulas；While the explosives PF-１，PF-２and PF-３are solidified by void vibration cast-ing，the densities ofΦ５０mm explosive cylinders are about１．６９３g／cm３，the detonation velocities are between７．８００－８．０００mm／μs，and the detonation pressures are about２４GPa．The explosive PF-３with B／Al compound powder mass ratio of１∶１and mass fraction of２０％，the combination effect of metalized explosive leads a little of B／Al compound powder to take reaction in reaction area，comparing to other formulas，the detonation velocity and detonation pressure of explosive are higher．It indicates that the spring electric pin method can be an additional method for detonation velocity measurement，and it can be adopted if copper foil electric pin method can′t be taken．
Ｋｅｙｗｏｒｄｓ：explosive containing B／Al；spring electric pin method；detonation velocity；detonation pressure
收稿日期：２０１７-０８-２５； 修回日期：２０１７-０９-３０
基金项目：国家自然科学基金面上项目（No．１１５７２３５９）；国家自然科学基金青年项目（No．１１５０２２４９；No．１１６０２２３８）；中物院发展基金资助（No．２０１５B０１０１０１２）
作者简介：李兴隆（１９８８－），男，博士，研究实习员，从事弹药工程与数值模拟研究。E-mail：lixinglong．sj＠１６３．com
通信作者：高大元（１９６２－），男，博士，副研究员，从事含能材料的热分析、爆轰和安全性能研究。E-mail：g aody４６６＠１６３．com
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